Kinetic modeling of catalytic transformation of methanol and ethanol into hydrocarbons: a review

Authors

  • Nabila Tabassum
  • Syed Saif Ali
  • Dr. Hasan Akhtar Zaidi

DOI:

https://doi.org/10.46243/jst.2021.v6.i04.pp136-144

Keywords:

Kinetic Modeling, Methanol, Ethanol, Lumped-Parameter Model, Langmuir-Hinshelwood model

Abstract

Several studies have been conducted on the methanol and ethanol conversion to hydrocarbons or olefins. Kinetic modeling helps researchers in interpreting the mechanism of a catalytic reaction and simulating experimental effects. Theoretical methods are valuable tools in this context for investigating experimental results related to mechanism or reactivity. The deterministic kinetic modeling incorporates theory and experimental results, allowing it to illustrate a catalyst in industrial conditions. This review included different kinetic models including the Lumped-Parameter model and Langmuir-Hinshelwood model

References

H. Heriyanto, O. Muraza, G.A. Nasser, M.A. Sanhoob, I.A. Bakare, B. Rochmadi, A. Budiman, Development of new kinetic models for methanol-to- hydrocarbons (MTH) over Ca-ZSM-5 catalyst, Energy & Fuels. 34 (2020) 6245–6260

M.K. Lee, J. Kim, J.H. Ryu, Y.S. Yoon, C.U. Kim, S.Y. Jeong, I.B. Lee, Modeling of Reaction and Deactivation Kinetics in Methanol-to-Olefins Reaction on SAPO-34, Ind. Eng. Chem. Res. 58 (2019) 13227–13238

G. Roohollahi, M. Kazemeini, A. Mohammadrezaee, R. Golhoseini, Application of a Simple Lumped Kinetic Model for the Catalytic Cracking Reaction of n-Butane Over the HZSM-5 Zeolite, Procedia Eng. 42 (2012) 140–147

S. Standl, F.M. Kirchberger, T. Kühlewind, M. Tonigold, M. Sanchez-Sanchez, J.A. Lercher, O. Hinrichsen, Single-event kinetic model for methanol-to-olefins (MTO) over ZSM-5: Fundamental kinetics for the olefin co-feed reactivity, Chem. Eng. J. 402 (2020) 126023

S.D.S. Asaee, L. Vafajoo, F. Khorasheh, A new approach to estimate parameters of a lumped kinetic model for hydroconversion of heavy residue, Fuel. 134 (2014) 343–353

K.V. Kumar, K. Porkodi, F. Rocha, Langmuir–Hinshelwood kinetics–A theoretical study, Catal. Commun. 9 (2008) 82–84

L. Ying, X. Yuan, M. Ye, Y. Cheng, X. Li, Z. Liu, A seven lumped kinetic model for industrial catalyst in DMTO process, Chem. Eng. Res. Des. 100 (2015) 179–191

A.T. Aguayo, D. Mier, A.G. Gayubo, M. Gamero, J. Bilbao, Kinetics of Methanol Transformation into Hydrocarbons on a HZSM-5 Zeolite Catalyst at High Temperature (400-550°C), Ind. Eng. Chem. Res. 49 (2010) 12371–12378

C.L. Chang, A.L. DeVera, D.J. Miller, A lumped kinetic model for dehydration of ethanol to hydrocarbons over HZSM-5, Chem. Eng. Commun. 95 (1990) 27–39

J. Becerra, E. Quiroga, E. Tello, M. Figueredo, M. Cobo, Kinetic modeling of polymer-grade ethylene production by diluted ethanol dehydration over H-ZSM-5 for industrial design, J. Environ. Chem. Eng. 6 (2018) 6165–6174

C.D. Chang, A kinetic model for methanol conversion to hydrocarbons, Chem. Eng. Sci. 35 (1980) 619–622

A.T. Aguayo, A.G. Gayubo, M. Castilla, J.M. Arandes, M. Olazar, J. Bilbao, MTG Process in a Fixed-Bed Reactor. Operation and Simulation of a Pseudoadiabatic Experimental Unit, Ind. Eng. Chem. Res. 40 (2001) 6087–6098

A.G. Gayubo, A.T. Aguayo, M. Castilla, A.L. Moran, J. Bilbao, Role of water in the kinetic modeling of methanol transformation into hydrocarbons on HZSM-5 zeolite, Chem. Eng. Commun. 191 (2004) 944–967

H.A. Zaidi, K.K. Pant, Combined experimental and kinetic modeling studies for the conversion of gasoline range hydrocarbons from methanol over modified HZSM-5 catalyst, Korean J. Chem. Eng. 27 (2010) 1404–1411

N. Li, C. Meng, D. Liu, Deactivation kinetics with activity coefficient of the methanol to aromatics process over modified ZSM-5, Fuel. 233 (2018) 283–290

A.T. Aguayo, A.G. Gayubo, A. Atutxa, M. Olazar, J. Bilbao, Catalyst Deactivation by Coke in the Transformation of Aqueous Ethanol into Hydrocarbons. Kinetic Modeling and Acidity Deterioration of the Catalyst, Ind. Eng. Chem. Res. 41 (2002) 4216–4224

A.G. Gayubo, A. Alonso, B. Valle, A.T. Aguayo, J. Bilbao, Kinetic Model for the Transformation of Bioethanol into Olefins over a HZSM- 5 Zeolite Treated with Alkali, Ind. Eng. Chem. Res. 49 (2010) 10836–10844

A.G. Gayubo, A. Alonso, B. Valle, A.T. Aguayo, M. Olazar, J. Bilbao, Kinetic modelling for the transformation of bioethanol into olefins on a hydrothermally stable Ni–HZSM-5 catalyst considering the deactivation by coke, Chem. Eng. J. 167 (2011) 262–277

Published

2021-08-13

How to Cite

Nabila Tabassum, Syed Saif Ali, & Akhtar Zaidi, D. H. (2021). Kinetic modeling of catalytic transformation of methanol and ethanol into hydrocarbons: a review. Journal of Science & Technology , 5(4), 136–144. https://doi.org/10.46243/jst.2021.v6.i04.pp136-144